2025 Women’s Copa Libertadores Semifinals: Matches, Predictions, and Where to Watch!

All good things come to an end, right? That can definitely be said about the top women’s football competition in South America, as the 2025 Women’s Copa Libertadores Semifinals will take place this Wednesday, October 15, defining which team will become continental champions — and bringing plenty of excitement for Sports Betting fans as well!

Colo-Colo and Deportivo Cali will try to bring a second Libertadores title to Chile and Colombia. On the other side of the bracket, Corinthians and Ferroviária battle it out to see which Brazilian club will continue their chase for yet another trophy.

If you’re counting down the seconds to kickoff, don’t worry: we’ve prepared this complete guide with everything you need to know about the 2025 Women’s Copa Libertadores Semifinals. Remember that the odds in this guide are only indicators of favoritism — not guarantees of results — and can change as bets are placed!

Colo-Colo vs Deportivo Cali

Ready to meet the first 2025 Women’s Libertadores finalist? Colo-Colo and Deportivo Cali will face each other this Wednesday, October 15, at 4:00 p.m. (local time). The match will be held at Estadio Francisco Urbano Morón, in Buenos Aires, and will determine who continues the mission of ending Brazil’s six-title streak in the tournament.

The Chilean side boasts the best defense in the competition and has not conceded a single goal so far. Led by Brazilian coach Tatiele Silveira, Las Albas are chasing their second Libertadores crown — 13 years after defeating Foz Cataratas in the final.

Las Verdiblancas are not far behind either: they have only conceded one goal and rely on a collective attacking effort. Their mission is to emulate Atlético Huila’s historic 2018 triumph, when the Colombian side claimed the country’s only women’s continental title by beating Santos in the final.

Colo-Colo’s Form

Colo-Colo boasts the best defense in the Libertadores, with zero goals conceded in four matches. This historic defensive record is due to the solid backline anchored by goalkeeper Ryan Torrero, right-back Michelle Olivares, and center-back Camila Martins.

Forward Mary Valencia is the team’s standout player, having scored all five of Colo-Colo’s goals in the tournament. Despite her dominance, coach Tatiele Silveira faces the challenge of ensuring her attack doesn’t rely solely on Valencia’s performance.

Deportivo Cali’s Form

Deportivo Cali’s main strength is also its defensive solidity: they have conceded just one goal, in their opening match — a 1-1 draw against Libertad. Center-back Kelly Caicedo, left-back Angie Salazar, and goalkeeper Luisa Agudelo have been key to maintaining that record.

Forward María Marquínez, who scored against São Paulo, leads the offensive line. Midfielder Paola García is another crucial figure for coach Jhon Ortiz, who will have a full squad available for this decisive match.

Head-to-Head Record

Colo-Colo and Deportivo Cali have never met in women’s football. In the men’s game, however, the advantage belongs to the Colombians: in four encounters, Deportivo Cali won three and lost only one — a 1-0 defeat in the 1999 Libertadores. Their last meeting was in 2004.

Predictions

As the only team with a perfect record, Colo-Colo enters as the betting favorite. Their win odds are at 1.88, while Deportivo Cali’s victory pays 3.75. Due to both teams’ strong defenses, a draw is the second-most likely outcome, at 3.35.

Where to Watch

• Cable TV: SporTV and XSports
• Streaming: PlutoTV and NSorts
• YouTube: Cazé TV and Canal GOAT

Bet on Colo-Colo vs Deportivo Cali at Blaze!

Corinthians vs Ferroviária

Brazil’s dominance in the Women’s Libertadores continues, and the country is guaranteed a finalist in 2025 — either Corinthians or Ferroviária. The match will take place at Estadio Florencio Sola, in Banfield, this Wednesday, October 15, at 8:00 p.m.

Boasting the best attack of the tournament with 17 goals, the Brabas come off a 4–0 rout over Boca Juniors. Winners of the last two editions, the São Paulo side has a total of five continental titles and will look to move one step closer to their sixth.

Meanwhile, Ferroviária are in a rebuilding phase, seeking to regain their competitive edge in women’s football. The two-time champions from Araraquara aim to end a five-year title drought and hand Corinthians their first-ever semifinal elimination — and they have the quality to do it.

Corinthians’ Form

The Brabas remain unbeaten and feature the tournament’s top scorer, midfielder Gabi Zanotti, who netted a hat-trick against Boca Juniors and has six goals overall. Striker Andressa Alves, with three assists, is another standout player.

Coach Lucas Piccinato faces one injury concern: midfielder Vic Albuquerque, who sprained her knee against Santa Fe, is doubtful. Still, the team has plenty of talent available, including defender Mariza, left-back Tamires, and young stars Dayana Rodríguez and Jhonson.

Ferroviária’s Form

Coach Leonardo Mendes, who led Ferroviária to their first Libertadores title in 2015, returned four months ago to bring the team back on track. With three wins and one draw, the Guerreiras Grenás have had a strong campaign so far but now face their biggest test yet.

Midfielder Raquel, who scored and assisted against Independiente del Valle, is confirmed in the lineup. Forward Natalia Vendito, with 10 goals this season, is also in top form. With no absences, Ferroviária will rely on their experienced 38-year-old goalkeeper Luciana to try to stop the competition’s best attack.

Head-to-Head

Corinthians and Ferroviária are two of the biggest forces in Brazilian women’s football, and their rivalry is well established. In 36 official meetings, the Brabas have 27 wins, eight draws, and just one loss.

That lone Ferroviária victory came three years ago — a 2–1 result in the 2022 Paulista Championship. Since then, Corinthians have won six times, with three draws. In the Libertadores, they met in the 2019 final, which Corinthians won.

Predictions

According to bettors, Corinthians are strong favorites to reach yet another final: their win odds are at 1.43. A draw is priced at 4.2, while a Ferroviária victory pays 6.2.

Where to Watch

• Cable TV: SporTV and XSports
• Streaming: PlutoTV and NSorts
• YouTube: Cazé TV, Canal GOAT, and Meu Timão

Bet on Corinthians vs Ferroviária at Blaze!

Who’s Favored to Win the 2025 Women’s Copa Libertadores?

You can still bet on who will lift the trophy this weekend by visiting the Competitions section on Blaze’s 2025 Women’s Libertadores page. Corinthians are the favorites to win their sixth title, with odds of 1.9, followed by Colo-Colo at 3.5.

Ferroviária’s odds stand at 6.0 to crown their rebuilding phase with a third Libertadores title, while Deportivo Cali are seen as the underdogs with odds of 7.0 to win their first-ever continental trophy.

Bet on the Women’s Copa Libertadores at Blaze!

The journey doesn’t end for the four semifinalists — all teams will play again on October 18, either in the Grand Final or the Third Place Playoff. And don’t worry: betting on the tournament is fully authorized under Brazil’s Ordinance MESP 125/2024!

Before placing any bets, make sure to study the rules, stats, and data to plan your moves — our Sports Betting Encyclopedia can help you with that!

Also, understand all the financial and mental health risks involved, using only money you can afford to lose. Betting should never be treated as an investment or source of income — only as entertainment!

Four teams remain, and the excitement is only growing! Wear your responsibility jersey and bet on the 2025 Women’s Copa Libertadores at Blaze!